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Lecture 16

 

Energy sources

         Current energy sources

        Predominantly fossil fuels: 80à90 %

        Currently in use:

         Coal

         Oil

         Natural gas

        Future use: unconventional hydrocarbons

         Shale oil

         Tar sands

         Coalbed methane

         Gas hydrates

         Alternative Energy sources

        Nuclear Energy

         Fission – in use

         Fusion – under research

        Solar Energy

         Direct

         Photovoltaics

         Solar heating etc.

         Indirect

         Hydropower

         Wind

         OTEC etc.

         Biomass

        Geothermal

        Tidal

 

Nuclear Power

         Energy associated with nuclear bonds

         Nuclear Fission

        Thermal reactors – in use; limited potential

        Breeder reactors – not available, large potential

        Thorium reactors – not available, large potential

         Nuclear Fusion – very large potential, not ready

        Magnetic confinement

        Inertial confinement

Principles of nuclei (Fig. 1)

         Building blocks

        Proton

        Neutron

        Electron

         Z Proton number

         N Neutron number

         M Mass number

         E Electron number

 

Definitions

         Isotopes: nuclei which have the same number of protons, but differ in number of neutrons à different mass, same element àidentical chemical behavior

         Isobars: nuclei which have the same mass, but differ in composition of nucleus à same mass, different elements

         Isotones: nuclei which have same number of neutrons but differ in number of protons à different mass, different element

The atom

         Atom is made up of nucleus and surrounding electron shell

         Nucleus contains almost all of the mass

         Chemical reactions result by interaction of electrons

         Nuclear reactions involve the nucleus, which is positively charged

 

Binding energy changes with configuration of nuclides (Fig. 2)

 

Mass defect and binding energy

Example: 1H + 1n à 2H (=D)

mH + mn – mD = Dm

 

1.007825 + 1.008665 – 2.014102 = 2.388x10-3 amu

 

Observation: The mass of the building blocks is greater than the resulting nucleus

à Mass defect à Energy à E = mc2

 

The challenge in fusion

         Bring two nuclei together which have positive charges

         Steps:

        Remove electrons à Plasma

        Plasma is state of matter where electrons and nuclei are separated à needs very high temperatures (>10,000oC)

        Inject kinetic energy to overcome Coulomb repulsion (Fig. 3)

 

Energy Barrier

         Energy Barrier ~ 5 keV

         Ei = 3/2 kT

         k Boltzmann constant: 8.125x10-5 eV/deg

         à 40x106 oK needed

 

Current approach

         D-T reaction and breeding of tritium

         D+T à 4He + n + 17.6 MeV

         n + 6Li à 4He + T + 4.8 MeV

         n + 7Li à n + T + 4He – 2.7 MeV

 

         D in seawater: D/H = 1/6500

         Li: 6Li 7.4% 7Li = 92.6 %

 

Principal approaches in fusion

         Magnetic confinement – Tokamak Reactor (Fig. 4)

        Charged particles are deflected while moving through a magnetic field

        Build very strong, torroidal magnets which force charged particles to come together

         Inertial confinement – Laser approach (Fig. 5)

        Insert target gas into small container, surrounded by material which evaporates easily

        Bombard capsule with laser from all sides simultaneously

        Evaporation produces short pulses of extreme pressure on inside to cause fusion

 

Fusion - assessment

         Very large energy potential

         Plentiful source materials (D; Li) available

         Very demanding engineering challenges

        Magnetic confinement (Tokamak; ITER)

        Inertial confinement (Laser; NIF)

         Large facilities needed

         No radioactive end-product, but radioactive T used and high n flux à some radioactive by-product likely

         System under investigation, but not very close to being available à > 30 yrs away